Issue 42, 2018
From the journal:

Dalton Transactions

Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]†

Anders Reinholdt,a   Jesper Bendix, ORCID logo *a   Anthony F. Hill ORCID logo *b  and  Richard A. Manzanob  

* Corresponding authors

a Department of Chemistry, University of Copenhagen, Universitetsparken 5, Denmark
E-mail: bendix@kiku.dk

b Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, Australia
E-mail: a.hill@anu.edu.au

Abstract

The reaction of [Ru(CAuCl)Cl2(PCy3)2] with [W([triple bond, length as m-dash]CSnnBu3)(CO)2(Tp*)] (obtained from [W([triple bond, length as m-dash]CBr)(CO)2(Tp*)], nBuLi and ClSnnBu3) affords the heterotetrametallic bis(carbido) complex [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)] in which the two distinct μ-carbido ligands adopt linear and T-shaped geometry at carbon.

Graphical abstract: Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]

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Article information

DOI
https://doi.org/10.1039/C8DT03851A
Article type
Communication
Submitted
24 Sep 2018
Accepted
05 Oct 2018
First published
05 Oct 2018

Dalton Trans., 2018,47, 14893-14896

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Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]

A. Reinholdt, J. Bendix, A. F. Hill and R. A. Manzano, Dalton Trans., 2018, 47, 14893 DOI: 10.1039/C8DT03851A

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