Jump to main content
Jump to site search

Issue 42, 2018
Previous Article Next Article

Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]

Author affiliations

Abstract

The reaction of [Ru(CAuCl)Cl2(PCy3)2] with [W([triple bond, length as m-dash]CSnnBu3)(CO)2(Tp*)] (obtained from [W([triple bond, length as m-dash]CBr)(CO)2(Tp*)], nBuLi and ClSnnBu3) affords the heterotetrametallic bis(carbido) complex [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)] in which the two distinct μ-carbido ligands adopt linear and T-shaped geometry at carbon.

Graphical abstract: Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]

Back to tab navigation

Supplementary files

Publication details

The article was received on 24 Sep 2018, accepted on 05 Oct 2018 and first published on 05 Oct 2018


Article type: Communication
DOI: 10.1039/C8DT03851A
Citation: Dalton Trans., 2018,47, 14893-14896
  •   Request permissions

    Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]

    A. Reinholdt, J. Bendix, A. F. Hill and R. A. Manzano, Dalton Trans., 2018, 47, 14893
    DOI: 10.1039/C8DT03851A

Search articles by author

Spotlight

Advertisements