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Copper based coordination polymers based on metalloligands: Utilization as the heterogeneous oxidation catalysts

Abstract

This work presents synthesis and characterization of two Cu(II)-based coordination polymers prepared by utilizing two different Co(III)–based metalloligands offering appended arylcarboxylic acid groups. Both coordination polymers are three-dimensional in nature and present pores and channels filled with water molecules. Both coordination polymers function as the heterogeneous catalysts for the epoxidation of various olefins using O2 while employing isobutyraldehyde as the coreductor as well as peroxide-mediated oxidation of assorted benzyl alcohols. Catalytic results illustrate efficient oxidation reactions whereas hot-fltration test and leaching experiments assert true heterogeneous nature of the catalysis.

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Publication details

The article was received on 22 Sep 2018, accepted on 02 Nov 2018 and first published on 03 Nov 2018


Article type: Paper
DOI: 10.1039/C8DT03836H
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Copper based coordination polymers based on metalloligands: Utilization as the heterogeneous oxidation catalysts

    R. Gupta, G. Kumar and F. Hussain, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT03836H

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