Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [ZnIIReIV3] system

Adrián Sanchis-Perucho; Carlos Rojas-Dotti; Nicolás Moliner; José Martínez-Lillo

doi:10.1039/C8DT03728K

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Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [Zn^IIRe ^IV₃] system†

Adrián Sanchis-Perucho,

^a Carlos Rojas-Dotti,^a Nicolás Moliner

^a and José Martínez-Lillo

*^a

Author affiliations

* Corresponding authors

^a Instituto de Ciencia Molecular (ICMol)/Departament de Química Inorgànica, Universitat de València, c/Catedrático José Beltrán 2, 46980 Paterna, Valencia, Spain
E-mail: f.jose.martinez@uves

Abstract

The compound (NBu₄)₄[Zn^II{Re^IVCl₄(μ-ox)}₃] (1) [NBu₄⁺ = tetra-n-butylammonium cation and ox²⁻ = oxalate dianion] is the first example of an oxalato-bridged Zn^II system coordinated to a 5d metal ion that exhibits slow relaxation of magnetisation.

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Article information

DOI: https://doi.org/10.1039/C8DT03728K
Article type: Communication
Submitted: 14 Sep 2018
Accepted: 18 Oct 2018
First published: 19 Oct 2018

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Dalton Trans., 2019,48, 370-373

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Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [Zn^IIRe^IV₃] system

A. Sanchis-Perucho, C. Rojas-Dotti, N. Moliner and J. Martínez-Lillo, Dalton Trans., 2019, 48, 370 DOI: 10.1039/C8DT03728K

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Dalton Transactions