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Highly soluble Cu(I)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds

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Abstract

The synthesis of the air-stable and highly soluble Cu(I)-acetonitrile salts [Cu(CH3CN)3.5][FAl] (1) ([FAl] = FAl{OC(C6F10)(C6F5)}3) and [Cu(CH3CN)4][TEF] (2) ([TEF] = Al{OC(CF3)3}4) is presented. Compound 1 reacts with the organometallic polyphosphorus complexes [Cp2Mo2(CO)42-P2)] (A) and [(Cp*Fe(η5-P5)] (B) and salt 2 reacts with B to form one new (3) and three unprecedented (4–6) phosphorus-rich Cu(I) dimers with the general formulas [Cu2(μ,η11-A)22-A)2][FAl]2 (3), [Cu2(μ,η11-A)21-CH3CN)4][FAl]2 (4), [Cu2(μ,η11-B)21-CH3CN)4][FAl]2 (5) and [Cu2(μ,η11-B)21-CH3CN)4][TEF]2 (6).

Graphical abstract: Highly soluble Cu(i)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds

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Publication details

The article was received on 14 Sep 2018, accepted on 09 Oct 2018 and first published on 12 Oct 2018


Article type: Communication
DOI: 10.1039/C8DT03723J
Citation: Dalton Trans., 2018, Advance Article
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    Highly soluble Cu(I)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds

    M. Elsayed Moussa, M. Piesch, M. Fleischmann, A. Schreiner, M. Seidl and M. Scheer, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT03723J

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