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Germylene-sulfoxide as potential hemilabile ligands: Application in coordination chemistry

Abstract

We here describe the synthesis of heteroleptic organogermylenes containing a sulfoxide donor function for their application in coordination chemistry. While complexation reaction with [W(cod)(CO)4] and [Mo(nbd)(CO)4] afforded bis(germanium)(II) transition-metal complexes, a bidentate complex coordinated by the germanium(II) and the oxygen atom of the sulfinyl group was obtained from [Ru(PPh3)3Cl2].

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Publication details

The article was received on 11 Sep 2018, accepted on 04 Oct 2018 and first published on 04 Oct 2018


Article type: Paper
DOI: 10.1039/C8DT03669A
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Germylene-sulfoxide as potential hemilabile ligands: Application in coordination chemistry

    D. Madec, N. Lentz, S. Ladeira, A. Baceiredo and T. Kato, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT03669A

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