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Issue 44, 2018
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Germylene–sulfoxide as a potential hemilabile ligand: application in coordination chemistry

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Abstract

We describe here the synthesis of heteroleptic organogermylenes containing a sulfoxide donor function for their application in coordination chemistry. While complexation reaction with [W(cod)(CO)4] and [Mo(nbd)(CO)4] afforded bis(germanium)(II) transition-metal complexes, a bidentate complex coordinated by germanium(II) and the oxygen atom of the sulfinyl group was obtained from [Ru(PPh3)3Cl2].

Graphical abstract: Germylene–sulfoxide as a potential hemilabile ligand: application in coordination chemistry

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Publication details

The article was received on 11 Sep 2018, accepted on 04 Oct 2018 and first published on 04 Oct 2018


Article type: Paper
DOI: 10.1039/C8DT03669A
Citation: Dalton Trans., 2018,47, 15751-15756
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    Germylene–sulfoxide as a potential hemilabile ligand: application in coordination chemistry

    N. Lentz, S. Mallet-Ladeira, A. Baceiredo, T. Kato and D. Madec, Dalton Trans., 2018, 47, 15751
    DOI: 10.1039/C8DT03669A

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