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Issue 41, 2018
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Catalytic and stoichiometric flavanone oxidation mediated by nonheme oxoiron(IV) complexes as flavone synthase mimics: kinetic, mechanistic and computational studies

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Abstract

The present study describes the first example of the stoichiometric and catalytic oxidation of flavanone by synthetic nonheme oxoiron(IV) complexes and their precursor iron(II) complexes with m-CPBA as the terminal oxidant. These models, including detailed kinetic, mechanistic and computational studies, may serve as the biomimics of flavone synthase (FS) enzymes.

Graphical abstract: Catalytic and stoichiometric flavanone oxidation mediated by nonheme oxoiron(iv) complexes as flavone synthase mimics: kinetic, mechanistic and computational studies

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Publication details

The article was received on 30 Aug 2018, accepted on 12 Sep 2018 and first published on 13 Sep 2018


Article type: Communication
DOI: 10.1039/C8DT03519A
Citation: Dalton Trans., 2018,47, 14416-14420
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    Catalytic and stoichiometric flavanone oxidation mediated by nonheme oxoiron(IV) complexes as flavone synthase mimics: kinetic, mechanistic and computational studies

    R. Turcas, B. Kripli, A. A. A. Attia, D. Lakk-Bogáth, G. Speier, M. Giorgi, R. Silaghi-Dumitrescu and J. Kaizer, Dalton Trans., 2018, 47, 14416
    DOI: 10.1039/C8DT03519A

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