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Redox Active Ligand and Metal Cooperation for C(sp2)-H Oxidation: Extension of Galactose Oxidase Mechanism in Water-Mediated Amide Formation

Abstract

Redox interplay between ligand and metal can provide profound driving force for the promotion of unprecedented reactions. This work presents an intriguing water-assisted oxidative transformation of imine to amide with no formal change in the metal oxidation state in copper and nickel complexes of aminophenol ligand versus zinc analogue.

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Publication details

The article was received on 26 Aug 2018, accepted on 28 Sep 2018 and first published on 08 Oct 2018


Article type: Communication
DOI: 10.1039/C8DT03477J
Citation: Dalton Trans., 2018, Accepted Manuscript
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    Redox Active Ligand and Metal Cooperation for C(sp2)-H Oxidation: Extension of Galactose Oxidase Mechanism in Water-Mediated Amide Formation

    Z. Alaji, E. Safaei, H. Yi, A. Wojtczak, H. Cong and A. Lei, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT03477J

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