Jump to main content
Jump to site search

Issue 42, 2018
Previous Article Next Article

Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides

Author affiliations

Abstract

The reactions of the boraquanidinato germylene (i-Pr)2NB(NDmp)2Ge (1) (Dmp = 2,6-Me2C6H3) with RN3 and RNCS produced rare examples of Ge2N and Ge3S rings, while the treatment of 1 with RNCO led to an insertion into the N–Ge bond leading to a novel type of germylene stabilized within a six membered ring, i.e. [N(R)C(O)N(Dmp)B(N(i-Pr)2)N(Dmp)]Ge (R = t-Bu or Ad).

Graphical abstract: Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides

Back to tab navigation

Supplementary files

Publication details

The article was received on 16 Aug 2018, accepted on 27 Sep 2018 and first published on 27 Sep 2018


Article type: Communication
DOI: 10.1039/C8DT03357A
Citation: Dalton Trans., 2018,47, 14880-14883
  •   Request permissions

    Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides

    J. Böserle, G. Zhigulin, S. Ketkov, R. Jambor, A. Růžička and L. Dostál, Dalton Trans., 2018, 47, 14880
    DOI: 10.1039/C8DT03357A

Search articles by author

Spotlight

Advertisements