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Issue 41, 2018
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Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

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Abstract

The preparation of a novel H-bonding DBU-H+ BINOLate Rare Earth Metal complex enabled the synthesis of the first copper-Rare Earth Metal BINOLate complex (CuDBU-REMB). CuDBU-REMB was compared to the analogous Li complex using X-ray crystallography and Exchange NMR spectroscopy (EXSY). The results provide insight into the role of the secondary metal cation in the framework's stabilization.

Graphical abstract: Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

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Submitted
15 Aug 2018
Accepted
21 Aug 2018
First published
21 Aug 2018

Dalton Trans., 2018,47, 14408-14410
Article type
Communication
Author version available

Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

G. B. Panetti, J. R. Robinson, P. J. Carroll, M. R. Gau, B. C. Manor, P. J. Walsh and E. J. Schelter, Dalton Trans., 2018, 47, 14408 DOI: 10.1039/C8DT03335H

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