Jump to main content
Jump to site search


Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

Author affiliations

Abstract

The preparation of a novel H-bonding DBU-H+ BINOLate Rare Earth Metal complex enabled the synthesis of the first copper-Rare Earth Metal BINOLate complex (CuDBU-REMB). CuDBU-REMB was compared to the analogous Li complex using X-ray crystallography and Exchange NMR spectroscopy (EXSY). The results provide insight into the role of the secondary metal cation in the framework's stabilization.

Graphical abstract: Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

Back to tab navigation

Supplementary files

Publication details

The article was received on 15 Aug 2018, accepted on 21 Aug 2018 and first published on 21 Aug 2018


Article type: Communication
DOI: 10.1039/C8DT03335H
Citation: Dalton Trans., 2018, Advance Article
  •   Request permissions

    Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex

    G. B. Panetti, J. R. Robinson, P. J. Carroll, M. R. Gau, B. C. Manor, P. J. Walsh and E. J. Schelter, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT03335H

Search articles by author

Spotlight

Advertisements