Binding of halogens by a Cr8 metallacrown†
Abstract
A Cr8 metallacrown binds halogens X2 (Cl2, Br2 and I2) without loss of crystallinity; the binding has been studied by X-ray diffraction and thermodynamic techniques.
* Corresponding authors
a
School of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, UK
E-mail:
richard.winpenny@manchester.ac.uk
A Cr8 metallacrown binds halogens X2 (Cl2, Br2 and I2) without loss of crystallinity; the binding has been studied by X-ray diffraction and thermodynamic techniques.
D. F. Sava, N. Zheng, I. J. Vitórica-Yrezábal, G. A. Timco and R. E. P. Winpenny, Dalton Trans., 2018, 47, 13771 DOI: 10.1039/C8DT03172J
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