PbTeGeO6: polar rosiaite-type germanate featuring a two dimensional layered structure

Zhen Jia; Xingxing Jiang; Zheshuai Lin; Mingjun Xia

doi:10.1039/C8DT03136C

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PbTeGeO₆: polar rosiaite-type germanate featuring a two dimensional layered structure†

Zhen Jia,

^ab Xingxing Jiang,^b Zheshuai Lin^b and Mingjun Xia

*^b

Author affiliations

* Corresponding authors

^a College of Chemistry and Chemical Engineering, Dezhou University, Dezhou, China

^b Beijing Center for Crystal Research and Development, Key Laboratory of Functional Crystals and Laser Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: xiamingjun@mail.ipc.ac.cn

Abstract

Polar rosiaite-type germanate PbTeGeO₆ (PTGO) was grown from TeO₂ flux. It exhibits a two dimensional layered structure composed of [TeGeO₆]²⁻ sheets with Pb²⁺ separation between the sheets. The second harmonic generation intensity of the title compound is about 1.5 times that of KH₂PO₄. The first principles calculation was performed to investigate its electronic structure, refractive indices and nonlinear optical properties.

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Article information

DOI: https://doi.org/10.1039/C8DT03136C
Article type: Communication
Submitted: 01 Aug 2018
Accepted: 06 Sep 2018
First published: 10 Sep 2018

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Dalton Trans., 2018,47, 16388-16392

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PbTeGeO₆: polar rosiaite-type germanate featuring a two dimensional layered structure

Z. Jia, X. Jiang, Z. Lin and M. Xia, Dalton Trans., 2018, 47, 16388 DOI: 10.1039/C8DT03136C

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Dalton Transactions