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PbTeGeO6: polar rosiaite-type germanate featuring a two dimensional layered structure

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Abstract

Polar rosiaite-type germanate PbTeGeO6 (PTGO) was grown from TeO2 flux. It exhibits a two dimensional layered structure composed of [TeGeO6]2− sheets with Pb2+ separation between the sheets. The second harmonic generation intensity of the title compound is about 1.5 times that of KH2PO4. The first principles calculation was performed to investigate its electronic structure, refractive indices and nonlinear optical properties.

Graphical abstract: PbTeGeO6: polar rosiaite-type germanate featuring a two dimensional layered structure

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Publication details

The article was received on 01 Aug 2018, accepted on 06 Sep 2018 and first published on 10 Sep 2018


Article type: Communication
DOI: 10.1039/C8DT03136C
Citation: Dalton Trans., 2018, Advance Article
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    PbTeGeO6: polar rosiaite-type germanate featuring a two dimensional layered structure

    Z. Jia, X. Jiang, Z. Lin and M. Xia, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT03136C

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