Construction of uniform ZrO2 nanoshells by buffer solutions

Xian-Sen Tao; Yong-Gang Sun; Xi-Jie Lin; Lin-Lin Hu; Tian-Qi Sun; Dong Zhang; An-Min Cao; Li-Jun Wan

doi:10.1039/C8DT03091J

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Construction of uniform ZrO₂ nanoshells by buffer solutions†

Xian-Sen Tao,^ab Yong-Gang Sun,^ac Xi-Jie Lin,^ab Lin-Lin Hu,^ab Tian-Qi Sun,^ab Dong Zhang,^ab An-Min Cao

*^ab and Li-Jun Wan

*^ab

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Molecular Nanostructure and Nanotechnology and CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, People's Republic of China
E-mail: anmin_cao@iccas.ac.cn, wanlijun@iccas.ac.cn

^b University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China
E-mail: anmin_cao@iccas.ac.cn, wanlijun@iccas.ac.cn

^c School of Chemistry & Chemical Engineering, Yancheng Institute of Technology, Yancheng, People's Republic of China

Abstract

We identified that the growth kinetics of ZrO₂ could be well-tuned in a CH₃COOH–CH₃COONa based buffer solution, which provided an efficient way to build uniform ZrO₂ nanoshells on various substrates. Using this synthetic strategy, yolk–shell structured Pd@ZrO₂ is demonstrated as a promising catalyst for methane oxidation.

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Article information

DOI: https://doi.org/10.1039/C8DT03091J
Article type: Communication
Submitted: 28 Jul 2018
Accepted: 14 Aug 2018
First published: 14 Aug 2018

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Dalton Trans., 2018,47, 12843-12846

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Construction of uniform ZrO₂ nanoshells by buffer solutions

X. Tao, Y. Sun, X. Lin, L. Hu, T. Sun, D. Zhang, A. Cao and L. Wan, Dalton Trans., 2018, 47, 12843 DOI: 10.1039/C8DT03091J

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