Issue 38, 2018
From the journal:

Dalton Transactions

Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex†

Tobias Schindler,a   Albert Paparo, ORCID logo ‡a   Haruka Nishiyama,b   Thomas P. Spaniol, ORCID logo a   Hayato Tsurugi, ORCID logo b   Kazushi Mashima ORCID logo *b  and  Jun Okuda ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany
E-mail: jun.okuda@ac.rwth-aachen.de

b Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka, Japan
E-mail: mashima@chem.es.osaka-u.ac.jp

Abstract

Deprotonation of a formato ligand by a cis-coordinated propylidyne ligand in a tungsten(VI) complex [(OSSO)W([triple bond, length as m-dash]CEt)(OCHO)] (3) that contains a tetradentate bis(phenolato) ligand (OSSO = {1,4-dithiabutanediyl-2,2′-bis(4,6-di-tert-butyl-phenolato)}) gave the dioxo complex [(OSSO)WO2] (4) along with CO, ethylene and propylene as major products of decomposition.

Graphical abstract: Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex

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Article information

DOI
https://doi.org/10.1039/C8DT03056A
Article type
Communication
Submitted
26 Jul 2018
Accepted
28 Aug 2018
First published
28 Aug 2018

Dalton Trans., 2018,47, 13328-13331

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Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex

T. Schindler, A. Paparo, H. Nishiyama, T. P. Spaniol, H. Tsurugi, K. Mashima and J. Okuda, Dalton Trans., 2018, 47, 13328 DOI: 10.1039/C8DT03056A

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