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Issue 36, 2018
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Bisphosphine phenol and phenolate complexes of Mn(i): manganese(i) catalyzed Tishchenko reaction

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Abstract

We synthesized new organomanganese complexes using the phenolic “pincer” type ligand H-POP. The coordination chemistry of H-POP with Mn(I) was explored, revealing a wide range of binding motifs. Finally, we found that complex 1 catalyzes the formation of benzyl benzoate from benzaldehyde in a Tishchenko reaction.

Graphical abstract: Bisphosphine phenol and phenolate complexes of Mn(i): manganese(i) catalyzed Tishchenko reaction

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Supplementary files

Article information


Submitted
18 Jul 2018
Accepted
14 Aug 2018
First published
14 Aug 2018

Dalton Trans., 2018,47, 12652-12655
Article type
Communication

Bisphosphine phenol and phenolate complexes of Mn(I): manganese(I) catalyzed Tishchenko reaction

K. J. Kadassery, S. N. MacMillan and D. C. Lacy, Dalton Trans., 2018, 47, 12652
DOI: 10.1039/C8DT02933D

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