We synthesized new organomanganese complexes using the phenolic “pincer” type ligand H-POP. The coordination chemistry of H-POP with Mn(I) was explored, revealing a wide range of binding motifs. Finally, we found that complex 1 catalyzes the formation of benzyl benzoate from benzaldehyde in a Tishchenko reaction.
K. J. Kadassery, S. N. MacMillan and D. C. Lacy, Dalton Trans., 2018, 47, 12652 DOI: 10.1039/C8DT02933D
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