Jump to main content
Jump to site search

Issue 37, 2018
Previous Article Next Article

[Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite

Author affiliations

Abstract

Two new hexadecanuclear lanthanide complexes employing the 1,5-bis(salicylidene)carbohydrazide (H2bsc) ligand are reported herein. These polynuclear aggregates crystallize in the R[3 with combining macron] space group, which is unprecedented in a family of lanthanide complexes with such high nuclearity. Magnetic susceptibility measurements reveal weak intramolecular interactions between the magnetic centres, and in the case of compound 2 (DyIII), single-molecule magnet properties are observed.

Graphical abstract: [Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite

Back to tab navigation

Supplementary files

Publication details

The article was received on 26 Jun 2018, accepted on 17 Aug 2018 and first published on 20 Aug 2018


Article type: Communication
DOI: 10.1039/C8DT02609B
Dalton Trans., 2018,47, 12847-12851

  •   Request permissions

    [Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite

    P. Richardson, T. Hsu, C. Kuo, R. J. Holmberg, B. Gabidullin, M. Rouzières, R. Clérac, M. Murugesu and P. Lin, Dalton Trans., 2018, 47, 12847
    DOI: 10.1039/C8DT02609B

Search articles by author

Spotlight

Advertisements