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Issue 32, 2018
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Redox-mediated formation of plutonium oxide nanoparticles

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Abstract

Precipitates formed by the neutralisation of Pu(III), Pu(IV), Pu(V), and Pu(VI) solutions were characterised by HRTEM, SAXS, and XRD in the suspensions. PuO2 nanoparticles uniform in size (typical diameter around 2.5 nm) and phase composition were observed in all cases under equilibrium conditions. For Pu(VI), the precipitation reactions proceed via an intermediate product.

Graphical abstract: Redox-mediated formation of plutonium oxide nanoparticles

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Supplementary files

Article information


Submitted
11 Jun 2018
Accepted
09 Jul 2018
First published
09 Jul 2018

Dalton Trans., 2018,47, 11239-11244
Article type
Paper

Redox-mediated formation of plutonium oxide nanoparticles

A. Yu. Romanchuk, T. V. Plakhova, A. V. Egorov, T. B. Egorova, P. V. Dorovatovskii, Y. V. Zubavichus, A. A. Shiryaev and S. N. Kalmykov, Dalton Trans., 2018, 47, 11239
DOI: 10.1039/C8DT02396D

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