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Issue 30, 2018
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Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

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Abstract

In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N’-bis(p-tolyl)propanediimidate. Their corresponding rhodium(I) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N’-chelating ligand nacnac.

Graphical abstract: Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

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Publication details

The article was received on 09 May 2018, accepted on 22 Jun 2018 and first published on 22 Jun 2018


Article type: Paper
DOI: 10.1039/C8DT01875H
Citation: Dalton Trans., 2018,47, 10195-10205
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    Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

    M. A. Land, B. Huo, K. N. Robertson, K. E. O. Ylijoki, P. T. K. Lee, J. Areephong, D. Vidović and J. A. C. Clyburne, Dalton Trans., 2018, 47, 10195
    DOI: 10.1039/C8DT01875H

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