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Issue 31, 2018
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Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

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Abstract

The preparation and structural characterisation of three new heterobimetallic hydride complexes containing 3-centre,2-electron W–H–Cu bonds is reported. These complexes have been characterised by single crystal X-ray crystallography and multinuclear NMR spectroscopy. The bonding in these complexes has been analysed by DFT calculations.

Graphical abstract: Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

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Article information


Submitted
20 Apr 2018
Accepted
11 May 2018
First published
14 May 2018

Dalton Trans., 2018,47, 10595-10600
Article type
Paper

Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

A. Hicken, A. J. P. White and M. R. Crimmin, Dalton Trans., 2018, 47, 10595
DOI: 10.1039/C8DT01569D

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