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Issue 31, 2018
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Gold(iii) π complexes

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Abstract

π Hydrocarbons are widespread ligands and substrates in transition metal chemistry. Although gold(III) has been known for some time to efficiently activate alkenes and alkynes towards nucleophilic addition, and to readily promote the C–H auration of arenes, the corresponding π-complexes have remained elusive until recently. This frontier article highlights recent achievements in the preparation and characterization of gold(III) π complexes. The coordination of alkenes, alkynes and arenes to gold(III) is presented and discussed.

Graphical abstract: Gold(iii) π complexes

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Article information


Submitted
13 Apr 2018
Accepted
07 May 2018
First published
16 May 2018

Dalton Trans., 2018,47, 10388-10393
Article type
Frontier

Gold(III) π complexes

C. Blons, A. Amgoune and D. Bourissou, Dalton Trans., 2018, 47, 10388
DOI: 10.1039/C8DT01457D

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