Cd2NF, an analogue of CdO

Krishnappa Manjunath; Suchitra Prasad; Umesh V. Waghmare; C. N. R. Rao

doi:10.1039/C8DT01137K

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Cd₂NF, an analogue of CdO†

Krishnappa Manjunath,^a Suchitra Prasad,^b Umesh V. Waghmare^b and C. N. R. Rao

*^a

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* Corresponding authors

^a New Chemistry Unit, International Centre for Materials Science, Sheikh Saqr Laboratory, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore-560064, India
E-mail: cnrrao@jncasr.ac.in
Web: http://www.jncasr.ac.in/cnrrao/

^b Theoretical Sciences Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore-560064, India

Abstract

Cd₂NF, isoelectronic with CdO, has been prepared by ammonolysis of CdF₂. Cd₂NF has the rock salt structure of CdO and shows electronic properties similar to CdO. First principles calculations shed light on the electronic structure and properties.

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Article information

DOI: https://doi.org/10.1039/C8DT01137K
Article type: Paper
Submitted: 24 Mar 2018
Accepted: 06 May 2018
First published: 08 Jun 2018

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Dalton Trans., 2018,47, 9303-9309

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Cd₂NF, an analogue of CdO

K. Manjunath, S. Prasad, U. V. Waghmare and C. N. R. Rao, Dalton Trans., 2018, 47, 9303 DOI: 10.1039/C8DT01137K

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