Issue 8, 2018

N,N-Disubstituted-N′-acylthioureas as modular ligands for deposition of transition metal sulfides

Abstract

First row transition metal complexes (Ni, Co, Cu, Zn) with N,N-disubstituted-N′-acylthiourea ligands have been synthesized and characterized. Bis(N,N-diisopropyl-N′-cinnamoylthiourea)nickel was found to have the lowest onset temperature for thermal decomposition. Thin film deposition of Ni, Co, and Zn sulfides by aerosol assisted chemical vapor deposition from their respective N,N-diisopropyl-N′-cinnamoylthiourea complexes at 350 °C has been demonstrated.

Graphical abstract: N,N-Disubstituted-N′-acylthioureas as modular ligands for deposition of transition metal sulfides

Supplementary files

Article information

Article type
Paper
Submitted
22 Dec 2017
Accepted
28 Jan 2018
First published
29 Jan 2018

Dalton Trans., 2018,47, 2719-2726

N,N-Disubstituted-N′-acylthioureas as modular ligands for deposition of transition metal sulfides

Z. Ali, N. E. Richey, D. C. Bock, K. A. Abboud, J. Akhtar, M. Sher and L. McElwee-White, Dalton Trans., 2018, 47, 2719 DOI: 10.1039/C7DT04860B

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