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Issue 4, 2018
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Supramolecular self-assembly of heterobimetallic complexes: a new N,P-based, selective heteroditopic ligand

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Abstract

Pyrimidine-hydrazone and phosphole architectures have been combined to create a new heteroditopic ligand capable of forming heterobimetallic ZnII/PdII, PbII/PdII and CuII/PdII complexes in high yielding stepwise or one pot reactions. The catalytic activity of these complexes in Heck coupling and Miyaura borylation reactions was investigated.

Graphical abstract: Supramolecular self-assembly of heterobimetallic complexes: a new N,P-based, selective heteroditopic ligand

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Article information


Submitted
26 Nov 2017
Accepted
11 Dec 2017
First published
12 Dec 2017

Dalton Trans., 2018,47, 1053-1061
Article type
Paper

Supramolecular self-assembly of heterobimetallic complexes: a new N,P-based, selective heteroditopic ligand

D. J. Hutchinson, R. Clauss, M. Sárosi and E. Hey-Hawkins, Dalton Trans., 2018, 47, 1053
DOI: 10.1039/C7DT04449F

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