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Issue 20, 2018
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Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with the para-C–H of unprotected aniline

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Abstract

This paper presents a novel method for synthesizing para-aminobenzophenone and its derivatives (p-ABPs) using a coumarin-surfactant modified polyoxometalate as the catalyst. Preliminary mechanistic studies indicate that the reaction has undergone an oxidative cross dehydrogenative coupling process. This method has the advantages of an easy process, a convenient raw material source, safe and green oxidants, and tolerances of several functional groups.

Graphical abstract: Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with the para-C–H of unprotected aniline

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Publication details

The article was received on 07 Jul 2018, accepted on 11 Sep 2018 and first published on 12 Sep 2018


Article type: Communication
DOI: 10.1039/C8CY01423J
Citation: Catal. Sci. Technol., 2018,8, 5133-5136
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    Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with the para-C–H of unprotected aniline

    Q. Xu, G. Yu, M. Liu, C. Peng, M. K. Banks, W. Xu, R. Wu and Y. Lu, Catal. Sci. Technol., 2018, 8, 5133
    DOI: 10.1039/C8CY01423J

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