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Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with para-C–H of unprotected aniline

Abstract

This paper presents a novel method for synthesizing para-aminobenzophenone and its derivatives (p-ABPs) using a coumarin-surfactantmodified polyoxometalate as the catalyst. Preliminary mechanistic studies indicate that the reaction has undergone a oxidative cross dehydrogenative coupling process. This method has the advantages of easy process, convenient raw material source, safe and green oxidants, and tolerances of several functional group.

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Publication details

The article was accepted on 11 Sep 2018 and first published on 12 Sep 2018


Article type: Communication
DOI: 10.1039/C8CY01423J
Citation: Catal. Sci. Technol., 2018, Accepted Manuscript
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    Coumarin-surfactant modified polyoxometalate catalyzed cross dehydrogenative coupling of benzyl alcohol with para-C–H of unprotected aniline

    Q. Xu, G. Yu, M. Liu, C. Peng, M. K. Banks, W. Xu, Y. Lu and R. Wu, Catal. Sci. Technol., 2018, Accepted Manuscript , DOI: 10.1039/C8CY01423J

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