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Issue 33, 2018
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Iron oxidation dynamics vs. temperature of synthetic potassic-ferro-richterite: a XANES investigation

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Abstract

We investigated the oxidation behaviour of a synthetic potassic-ferro-richterite up to 750 °C by using simultaneous X-ray absorption spectroscopy and X-ray diffraction experiments with synchrotron radiation. From the X-ray diffraction results, we observed an abrupt decrease of cell dimensions at ∼335 °C accompanied by an anomalous increase in the monoclinic cell angle β. From the analysis of the XANES spectra at the iron K-edge, we observed that the structural shrinkage is due to the iron oxidation process, coupled to hydrogen loss, occurring at ∼315 °C, slightly before the cell contraction. Combining these results with previous studies performed on similar samples by single-crystal structure refinement, Mössbauer, high temperature-Fourier transform IR and Raman spectroscopies, we show that the temperature evolution in Fe-amphiboles is a multi-step process. Following the iron oxidation driven by temperature, the structural dynamics in this double-chain silicate is ruled by local strains in the ribbon of iron-filled octahedra, mainly due to the contraction of the M(1) site.

Graphical abstract: Iron oxidation dynamics vs. temperature of synthetic potassic-ferro-richterite: a XANES investigation

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Publication details

The article was received on 05 Jul 2018, accepted on 02 Aug 2018 and first published on 02 Aug 2018


Article type: Paper
DOI: 10.1039/C8CP04249G
Citation: Phys. Chem. Chem. Phys., 2018,20, 21764-21771
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    Iron oxidation dynamics vs. temperature of synthetic potassic-ferro-richterite: a XANES investigation

    G. Della Ventura, F. Galdenzi, G. Cibin, R. Oberti, W. Xu, S. Macis and A. Marcelli, Phys. Chem. Chem. Phys., 2018, 20, 21764
    DOI: 10.1039/C8CP04249G

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