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Issue 40, 2018
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Probing charge transfer characteristics in a donor–acceptor metal–organic framework by Raman spectroelectrochemistry and pressure-dependence studies

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Abstract

The stimuli responsive behaviour of charge transfer donor–acceptor metal–organic frameworks (MOFs) remains an understudied phenomenon which may have applications in tuneable electronic materials. We now report the modification of donor–acceptor charge transfer characteristics in a semiconducting tetrathiafulvalene–naphthalene diimide-based MOF under applied electrochemical bias and pressure. We employ a facile solid state in situ Raman spectroelectrochemical technique, applied for the first time in the characterisation of electroactive MOFs, to monitor the formation of a new complex TTFTC˙+–DPNI from a largely neutral system, upon electrochemical oxidation of the framework. In situ pressure-dependent Raman spectroscopy and powder X-ray diffraction experiments performed in a diamond anvil cell revealed blue shifts in the donor and acceptor vibrational modes in addition to contractions in the unit cell which are indicative of bond shortening. This study demonstrates the utility of in situ Raman spectroscopic techniques in the characterisation of redox-active MOFs and the elucidation of their electronic behaviours.

Graphical abstract: Probing charge transfer characteristics in a donor–acceptor metal–organic framework by Raman spectroelectrochemistry and pressure-dependence studies

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Article information


Submitted
01 Jul 2018
Accepted
04 Sep 2018
First published
10 Sep 2018

Phys. Chem. Chem. Phys., 2018,20, 25772-25779
Article type
Paper
Author version available

Probing charge transfer characteristics in a donor–acceptor metal–organic framework by Raman spectroelectrochemistry and pressure-dependence studies

P. M. Usov, C. F. Leong, B. Chan, M. Hayashi, H. Kitagawa, J. J. Sutton, K. C. Gordon, I. Hod, O. K. Farha, J. T. Hupp, M. Addicoat, A. B. Kuc, T. Heine and D. M. D’Alessandro, Phys. Chem. Chem. Phys., 2018, 20, 25772
DOI: 10.1039/C8CP04157A

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