Jump to main content
Jump to site search

Issue 44, 2018
Previous Article Next Article

Synthesis and functionalization of phase-pure NU-901 for enhanced CO2 adsorption: the influence of a zirconium salt and modulator on the topology and phase purity

Author affiliations

Abstract

The synthesis of NU-901, a microporous Zr6-based MOF with scu topology, often generates NU-1000 csq phase impurities. This work demonstrates that the use of certain Zr-salts and carboxylic acid modulators affects the formation of phase impurities. Phase-pure NU-901 was solvothermally synthesized and functionalized with amines through the use of solvent-assisted linker incorporation (SALI) resulting in more than double the typical CO2 adsorption capacity of NU-901.

Graphical abstract: Synthesis and functionalization of phase-pure NU-901 for enhanced CO2 adsorption: the influence of a zirconium salt and modulator on the topology and phase purity

Back to tab navigation

Supplementary files

Publication details

The article was received on 28 Aug 2018, accepted on 13 Oct 2018 and first published on 16 Oct 2018


Article type: Communication
DOI: 10.1039/C8CE01454J
Citation: CrystEngComm, 2018,20, 7066-7070
  •   Request permissions

    Synthesis and functionalization of phase-pure NU-901 for enhanced CO2 adsorption: the influence of a zirconium salt and modulator on the topology and phase purity

    S. J. Garibay, I. Iordanov, T. Islamoglu, J. B. DeCoste and O. K. Farha, CrystEngComm, 2018, 20, 7066
    DOI: 10.1039/C8CE01454J

Search articles by author

Spotlight

Advertisements