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Issue 34, 2018
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A pillar-layered porous CoII-MOF with dual active sites for selective gas adsorption

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Abstract

A pillar-layered microporous MOF (SD/Co3) has been constructed from trimeric {Co3(COO)6} clusters as SBUs and mixed ligands as linkers. It exhibits preferential selective adsorption of C2H2/C2H4, C2H2/C2H6 and CO2/N2, owing to its dual active sites including uncoordinated nitrogen sites from pyrimidine groups and unsaturated metal centres (UMCs) exposed in channels.

Graphical abstract: A pillar-layered porous CoII-MOF with dual active sites for selective gas adsorption

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Publication details

The article was received on 08 Jul 2018, accepted on 02 Aug 2018 and first published on 04 Aug 2018


Article type: Communication
DOI: 10.1039/C8CE01118D
Citation: CrystEngComm, 2018,20, 4905-4909

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    A pillar-layered porous CoII-MOF with dual active sites for selective gas adsorption

    X. Gao, S. Zhang, H. Yan, Y. Li, Q. Liu, X. Wang, C. Tung, H. Ma and D. Sun, CrystEngComm, 2018, 20, 4905
    DOI: 10.1039/C8CE01118D

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