Jump to main content
Jump to site search

Issue 34, 2018
Previous Article Next Article

A highly efficient heterogeneous catalyst of cobalt-based coordination polymers for aerobic epoxidation of cyclohexene

Author affiliations

Abstract

A novel heterogeneous catalyst of cobalt-based coordination polymers has been successfully fabricated using a tyrosine-based derivative. Heterogeneous catalytic experiments on allylic oxidation of cyclohexene indicate that the titled complexes present high catalytic activities using tert-butyl hydroperoxide (t-BuOOH) as an oxidant. The activation energy for the whole process of oxidation of cyclohexene has been calculated to be 25.5 kJ mol−1, which indicates the important role of the selected ancillary ligands in the synthesis of the heterogeneous catalyst.

Graphical abstract: A highly efficient heterogeneous catalyst of cobalt-based coordination polymers for aerobic epoxidation of cyclohexene

Back to tab navigation

Supplementary files

Publication details

The article was received on 31 May 2018, accepted on 30 Jul 2018 and first published on 31 Jul 2018


Article type: Paper
DOI: 10.1039/C8CE00899J
Citation: CrystEngComm, 2018,20, 5074-5078
  •   Request permissions

    A highly efficient heterogeneous catalyst of cobalt-based coordination polymers for aerobic epoxidation of cyclohexene

    F. Yu, CrystEngComm, 2018, 20, 5074
    DOI: 10.1039/C8CE00899J

Search articles by author

Spotlight

Advertisements