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A Highly Efficient Heterogeneous Catalyst of Cobalt-based Coordination Polymer For Aerobic Epoxidation of Cyclohexene

Abstract

A novel heterogeneous catalyst of cobalt-based coordination polymer with tyrosine-based derivative had been successfully constructed. Heterogeneous catalytic experiments on allylic oxidation of cyclohexene indicate that titled complex present highly catalytic activity by utilizing the tert-butylhydroperoxide (t-BuOOH) as oxidant. The activation energy for the whole process of oxidation of cylcohexene had been calculated as 25.5 kJ mol-1, which indicate the important role of the selected ancillary ligands in the resulted heterogeneous catalyst.

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Publication details

The article was received on 31 May 2018, accepted on 30 Jul 2018 and first published on 31 Jul 2018


Article type: Paper
DOI: 10.1039/C8CE00899J
Citation: CrystEngComm, 2018, Accepted Manuscript
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    A Highly Efficient Heterogeneous Catalyst of Cobalt-based Coordination Polymer For Aerobic Epoxidation of Cyclohexene

    F. Yu, CrystEngComm, 2018, Accepted Manuscript , DOI: 10.1039/C8CE00899J

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