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Issue 28, 2018
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Solvent-induced structural transformation and magnetic modulation in 1D copper(II) polymers based on a semi-rigid ligand containing 4-amino-1,2,4-triazole

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Abstract

A helical Cu(II) polymer 1 exhibits reversible SCSC transformation and magnetism switch by the chemisorption/desorption of MeCN molecules. Significant changes in its color, coordination environment, and magnetic behavior were found during the SCSC transformation. In addition, the effect of different coordinated solvents on the magnetic properties was further investigated.

Graphical abstract: Solvent-induced structural transformation and magnetic modulation in 1D copper(ii) polymers based on a semi-rigid ligand containing 4-amino-1,2,4-triazole

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Publication details

The article was received on 18 May 2018, accepted on 12 Jun 2018 and first published on 13 Jun 2018


Article type: Communication
DOI: 10.1039/C8CE00820E
Citation: CrystEngComm, 2018,20, 3955-3959
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    Solvent-induced structural transformation and magnetic modulation in 1D copper(II) polymers based on a semi-rigid ligand containing 4-amino-1,2,4-triazole

    X. Wu, F. Pan, S. Yin, J. Ge, G. Jin, P. Wang and J. Ma, CrystEngComm, 2018, 20, 3955
    DOI: 10.1039/C8CE00820E

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