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Issue 21, 2018
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Single crystal-to-single crystal transformations induced by ammonia–water equilibrium changes

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Abstract

Reversible single crystal-to-single crystal transformations were observed for the Ni(II) complex with 5-methyl-5-phenylhydantoin. Moreover, the symmetry changes from triclinic (P[1 with combining macron]) to monoclinic (P21/c). The change is induced by a disturbance of the ammonia–water equilibrium between the [solid state–solution-gas] phases, which causes an exchange of the solvent in the crystal structure.

Graphical abstract: Single crystal-to-single crystal transformations induced by ammonia–water equilibrium changes

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Article information


Submitted
14 Mar 2018
Accepted
26 Apr 2018
First published
26 Apr 2018

CrystEngComm, 2018,20, 2907-2911
Article type
Communication

Single crystal-to-single crystal transformations induced by ammonia–water equilibrium changes

M. Daszkiewicz, M. Puszyńska-Tuszkanow, Z. Staszak, I. Chojnacka, H. Fałtynowicz and M. Cieślak-Golonka, CrystEngComm, 2018, 20, 2907
DOI: 10.1039/C8CE00401C

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