Issue 35, 2018

Conformational chiral polymorphism in cis-bis-triphenylphosphine complexes of transition metals

Abstract

The structure of cis-[Mo(CO)4(PPh3)2] 1 was determined by F. A. Cotton, D. J. Darensbourg, S. Klein and B. W. S. Kolthammer, Inorg. Chem., 1982, 21, 1651–1655, with the space group P[1 with combining macron]. A second polymorph 2 is reported here, with the space group P21/c. The compounds differ in the interactions between the conformational chiral triphenylphosphine groups. In 1, there is π–π stacking between adjacent phenyl groups, whereas in 2, there are σ–π interactions instead. A search of the Cambridge Structural Database reveals that this is a relatively frequent occurrence in cis-bis-triphenylphosphine complexes and the phenomenon can be analysed by means of the C(ipso)–P–M–P torsion angles. The majority of compounds fall in the π–π stacking data area with torsion angles of 10–15° and 55–60°; however, for octahedrally coordinated metals, the optimum is a σ–π interaction at 40°/40°. This corresponds well to the values in 2: 46°/40°, but for 1, we instead find the torsion angles to be 11°/18°. There is indeed a small occurrence of these values as well in the data, and it appears that for 1, this conformation is stabilised by weak CO⋯H–C hydrogen bonds. Density functional theory (DFT) calculations indicate that 1 is the more stable polymorph by 72 kJ mol−1 but that the strain of the complexes (the difference between a relaxed molecule in the respective conformation and the structure in the crystal) is larger for 1 than for 2, further indicating that a special intermolecular interaction is responsible for the stability of this polymorph. In both polymorphs, the triphenylphosphines have the same conformational chirality, consistent with single-molecule calculations that predict racemic conformations to be substantially higher in energy for both σ–π interactions (+17 kJ mol−1) and π–π stacking (+30 kJ mol−1).

Graphical abstract: Conformational chiral polymorphism in cis-bis-triphenylphosphine complexes of transition metals

Supplementary files

Article information

Article type
Paper
Submitted
02 Mar 2018
Accepted
01 Jun 2018
First published
08 Jun 2018
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2018,20, 5137-5142

Conformational chiral polymorphism in cis-bis-triphenylphosphine complexes of transition metals

N. Tshabang, G. P. Makgatle, S. A. Bourne, N. Kann, J. D. Evans, F. Coudert and L. Öhrström, CrystEngComm, 2018, 20, 5137 DOI: 10.1039/C8CE00337H

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