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Issue 8, 2019
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Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction

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Abstract

Various carbonyl-bridged dibenzofulvalenes were synthesized by a sequence of rhodium-catalyzed stitching reaction and post-functionalization, and their optical and electronic properties could be tuned by changing the terminal substituents. The present stitching reaction also allowed for facile synthesis of dibenzofulvalenes having C, Si, Ge, S, and P as the bridging elements.

Graphical abstract: Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction

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Article information


Submitted
15 Dec 2018
Accepted
28 Dec 2018
First published
29 Dec 2018

Chem. Commun., 2019,55, 1072-1075
Article type
Communication

Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction

R. Shintani, S. Kishikawa, K. Nakamura, T. Tsuda and K. Nozaki, Chem. Commun., 2019, 55, 1072
DOI: 10.1039/C8CC09943J

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