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Issue 100, 2018
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Carbon–nitrogen bond cleavage of pyridine with two molecular substituted allenoates: access to 2-arylpyrimidin-4(3H)-one

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Abstract

A DABCO-catalyzed annulation reaction of pyridin-2-amine and substituted allenoates has been disclosed. This strategy allows for the ring-opening of a pyridine ring system and the formation of two new rings including a pyrimidinone ring and a benzene ring in an efficient manner.

Graphical abstract: Carbon–nitrogen bond cleavage of pyridine with two molecular substituted allenoates: access to 2-arylpyrimidin-4(3H)-one

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Publication details

The article was received on 10 Nov 2018, accepted on 23 Nov 2018 and first published on 23 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC08946A
Citation: Chem. Commun., 2018,54, 14128-14131
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    Carbon–nitrogen bond cleavage of pyridine with two molecular substituted allenoates: access to 2-arylpyrimidin-4(3H)-one

    T. Jin, H. Yuan, S. Su, X. Jia, C. Li, J. Li and J. Fang, Chem. Commun., 2018, 54, 14128
    DOI: 10.1039/C8CC08946A

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