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Issue 14, 2019
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Rhodium(III)-catalyzed sulfonamide directed ortho C–H carbenoid functionalization via metal carbene migratory insertion

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Abstract

A rhodium(III)-catalyzed sulfonamide directed ortho C–H carbenoid functionalization has been developed with good yields. This method is attractive due to its broad substrate scope, and enables derivation of diverse biologically active sulfonamide structures and late-stage modification of sulfa drugs.

Graphical abstract: Rhodium(iii)-catalyzed sulfonamide directed ortho C–H carbenoid functionalization via metal carbene migratory insertion

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Publication details

The article was received on 06 Nov 2018, accepted on 05 Dec 2018 and first published on 06 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC08837C
Citation: Chem. Commun., 2019,55, 2027-2030

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    Rhodium(III)-catalyzed sulfonamide directed ortho C–H carbenoid functionalization via metal carbene migratory insertion

    Y. Dong, J. Chen and H. Xu, Chem. Commun., 2019, 55, 2027
    DOI: 10.1039/C8CC08837C

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