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Issue 5, 2019
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Rhodium(III) vs. cobalt(III): a mechanistically distinct three-component C–H bond addition cascade using a Cp*RhIII catalyst

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Abstract

Three-component C–H bond additions across two different coupling partners remain underdeveloped. Herein, we report the first three-component RhIII-catalyzed C–H bond additions to a wide range of dienes and aldehydes. Our method constitutes a complementary access with Ellman's CoIII-catalytic system to homoallylic alcohols.

Graphical abstract: Rhodium(iii) vs. cobalt(iii): a mechanistically distinct three-component C–H bond addition cascade using a Cp*RhIII catalyst

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Publication details

The article was received on 04 Nov 2018, accepted on 07 Dec 2018 and first published on 08 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC08792J
Chem. Commun., 2019,55, 695-698

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    Rhodium(III) vs. cobalt(III): a mechanistically distinct three-component C–H bond addition cascade using a Cp*RhIII catalyst

    R. Li, C. Ju and D. Zhao, Chem. Commun., 2019, 55, 695
    DOI: 10.1039/C8CC08792J

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