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Rhodium(III) vs. Cobalt(III): Mechanistically Distinct Three-Component C–H Bond Addition Cascade using Cp*RhIII Catalyst

Abstract

Three-component C–H bond addition across two different coupling partners remain underdeveloped. Herein, we report the first three-component RhIII-catalyzed C–H bond additions to a wide range of dienes and aldehydes. Our method constitutes a complementary access with Ellman’s CoIII-catayltic system to homoallylic alcohols.

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Publication details

The article was received on 04 Nov 2018, accepted on 07 Dec 2018 and first published on 08 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC08792J
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Rhodium(III) vs. Cobalt(III): Mechanistically Distinct Three-Component C–H Bond Addition Cascade using Cp*RhIII Catalyst

    R. Li, C. Ju and D. Zhao, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC08792J

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