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Issue 99, 2018
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Achievement of ligand-field induced thermochromic luminescence via two-step single-crystal to single-crystal transformations

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Abstract

We report here a new approach to achieve thermochromic luminescence through thermally induced ligand-field transformations. A one-dimensional chain manganese(II) complex exhibits thermochromic luminescence from blue-green (502 nm) to red (617 nm) emission in a wide range of temperatures (480–80 K), ascribed to the conversion of a tetrahedronal to trigonal bipyramidal ligand-field via two-step single-crystal to single-crystal transformations.

Graphical abstract: Achievement of ligand-field induced thermochromic luminescence via two-step single-crystal to single-crystal transformations

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Publication details

The article was received on 30 Oct 2018, accepted on 19 Nov 2018 and first published on 20 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC08665F
Citation: Chem. Commun., 2018,54, 13961-13964
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    Achievement of ligand-field induced thermochromic luminescence via two-step single-crystal to single-crystal transformations

    Y. Wu, X. Zhang, Y. Zhang, M. Yang and Z. Chen, Chem. Commun., 2018, 54, 13961
    DOI: 10.1039/C8CC08665F

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