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Issue 99, 2018
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Nickel-catalysed decarbonylative borylation of aroyl fluorides

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Abstract

The first Ni(cod)2/PPh3 catalyst system has been established for decarbonylative borylation of aroyl fluorides with bis(pinacolato)diboron. A wide range of functional groups in the substrates were well tolerated. The ease of access of the starting aroyl fluorides indicates that these results might become an alternative to the existing decarbonylation events.

Graphical abstract: Nickel-catalysed decarbonylative borylation of aroyl fluorides

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Publication details

The article was received on 24 Oct 2018, accepted on 20 Nov 2018 and first published on 20 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC08504H
Citation: Chem. Commun., 2018,54, 13969-13972
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    Nickel-catalysed decarbonylative borylation of aroyl fluorides

    Z. Wang, X. Wang and Y. Nishihara, Chem. Commun., 2018, 54, 13969
    DOI: 10.1039/C8CC08504H

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