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Visible-light mediated carbamoyl radical addition to heteroarenes

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Abstract

The generation of carbamoyl radicals, followed by their addition to heteroarenes, was performed under mild conditions through a metal-free photocatalyzed decarboxylation of oxamic acids. The process has been applied to the carbamoylation of heteroaromatic bases using α-aminoacid-derived oxamic acids, leading to the corresponding amides without racemization.

Graphical abstract: Visible-light mediated carbamoyl radical addition to heteroarenes

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Publication details

The article was received on 17 Oct 2018, accepted on 05 Dec 2018 and first published on 06 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC08326F
Citation: Chem. Commun., 2019, Advance Article
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    Visible-light mediated carbamoyl radical addition to heteroarenes

    A. H. Jatoi, G. G. Pawar, F. Robert and Y. Landais, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC08326F

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