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A nonpolar solvent effect by CH/π interaction inside zeolites: characterization, mechanism and concept

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Abstract

The acidity enhancement induced by the nonpolar solvent effect of naphthalene inside zeolites was unambiguously identified. The mechanism of such an effect due to the CH/π interaction in the nonpolar environment has been revealed based on the advanced 2D 1H–13C correlation NMR technique and DFT calculations for the first time.

Graphical abstract: A nonpolar solvent effect by CH/π interaction inside zeolites: characterization, mechanism and concept

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Publication details

The article was received on 17 Oct 2018, accepted on 05 Nov 2018 and first published on 05 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC08310J
Citation: Chem. Commun., 2018, Advance Article
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    A nonpolar solvent effect by CH/π interaction inside zeolites: characterization, mechanism and concept

    G. Li, L. Huang, X. Yi, Y. Peng, S. C. E. Tsang and A. Zheng, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC08310J

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