Issue 96, 2018

Copper-catalyzed oxidative intermolecular 1,2-alkylarylation of styrenes with ethers and indoles

Abstract

A new copper-catalyzed oxidative three-component intermolecular 1,2-alkylarylation of styrenes with ethers and indoles is disclosed. This method utilizes TBPB as an oxidant to efficiently construct C(sp3)–C(sp3) and C(sp3)–C(sp2) bonds in one step through probable radical and electrophilic alkylation processes, respectively, and a variety of functional groups are well tolerated.

Graphical abstract: Copper-catalyzed oxidative intermolecular 1,2-alkylarylation of styrenes with ethers and indoles

Supplementary files

Article information

Article type
Communication
Submitted
16 Oct 2018
Accepted
05 Nov 2018
First published
06 Nov 2018

Chem. Commun., 2018,54, 13511-13514

Copper-catalyzed oxidative intermolecular 1,2-alkylarylation of styrenes with ethers and indoles

R. Su, Y. Li, M. Min, X. Ouyang, R. Song and J. Li, Chem. Commun., 2018, 54, 13511 DOI: 10.1039/C8CC08274J

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