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Binding for endohedral-metallofullerene superatoms induced by magnetic coupling

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Abstract

To design new materials based on artificial superatoms, clarifying their involved interaction is particularly important. In this study, we discuss first-principle calculations to show that the interaction between endohedral metallofullerenes (EMFs) of U@C28 can lead to different chemical and physical adsorption structures. Especially, these structures are derived from different magnetic coupling resonances, and they can transform by changing the distance between U@C28 superatoms. These findings will promote the future development for bottom-up assembling of new functional materials and even devices.

Graphical abstract: Binding for endohedral-metallofullerene superatoms induced by magnetic coupling

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Publication details

The article was received on 13 Oct 2018, accepted on 29 Oct 2018 and first published on 29 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC08200F
Citation: Chem. Commun., 2018, Advance Article
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    Binding for endohedral-metallofullerene superatoms induced by magnetic coupling

    W. Xie, W. Jiang, Y. Gao, J. Wang and Z. Wang, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC08200F

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