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Issue 92, 2018
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Ca(II), Yb(II) and Tm(III) complexes with tri- and tetra-anions of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene

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Abstract

Reduction of [(dpp-bian)2−M2+(thf)4] (M = Ca, 1; Yb, 6; dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) by alkali metals results in heterometallic, [(dpp-bian)3−M2+K+(thf)2]2 (M = Ca, 2; Yb, 7), [(dpp-bian)4−Ca2+A2+(thf)4]2 (A = Na, 3; Li, 4; K, 5), [(dpp-bian)4−Yb2+K2+(thf)4]2 (8) and [(dpp-bian)24−Yb32+K2+(thf)8] (9). The reduction of [(dpp-bian)TmBr(thf)n] (in situ) affords [(dpp-bian)4−Tm3+Na+(thf)]2 (10).

Graphical abstract: Ca(ii), Yb(ii) and Tm(iii) complexes with tri- and tetra-anions of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene

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Publication details

The article was received on 13 Oct 2018, accepted on 22 Oct 2018 and first published on 01 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC08108E
Citation: Chem. Commun., 2018,54, 12950-12953
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    Ca(II), Yb(II) and Tm(III) complexes with tri- and tetra-anions of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene

    I. L. Fedushkin, D. A. Lukina, A. A. Skatova, A. N. Lukoyanov and A. V. Cherkasov, Chem. Commun., 2018, 54, 12950
    DOI: 10.1039/C8CC08108E

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