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Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

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Abstract

The direct olefination of aryl/alkyl halides with trimethylsilyldiazomethane (TMSD) as a C1- or C2-unit was achieved successfully via a metal carbene migratory insertion process, which offered a new access to afford (E)-vinyl silanes and (E)-silyl-substituted α,β-unsaturated amides in good yields and high chemoselectivity.

Graphical abstract: Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

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Publication details

The article was received on 23 Sep 2018, accepted on 24 Oct 2018 and first published on 25 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC07664B
Citation: Chem. Commun., 2018, Advance Article
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    Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

    Q. Mu, X. Wang, F. Ye, Y. Sun, X. Bai, J. Chen, C. Xia and L. Xu, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC07664B

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