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Issue 95, 2018
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Highly-active, graphene-supported platinum catalyst for the solventless hydrosilylation of olefins

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Abstract

Herein we report the development of the first graphene-supported platinum catalyst that has demonstrated exceptional catalytic activity and stability for hydrosilylation reactions of olefins (TOF 4.8 × 106 h−1, TON = 9.4 × 106). The catalyst also exhibited functional group tolerance over a broad range of industrially relevant substrates with minimal metal leaching. In addition, the catalyst system was successfully translated into a packed bed platform for continuous hydrosilylation reactions.

Graphical abstract: Highly-active, graphene-supported platinum catalyst for the solventless hydrosilylation of olefins

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Publication details

The article was received on 21 Sep 2018, accepted on 30 Oct 2018 and first published on 02 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07641C
Citation: Chem. Commun., 2018,54, 13343-13346

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    Highly-active, graphene-supported platinum catalyst for the solventless hydrosilylation of olefins

    C. J. Kong, S. E. Gilliland, B. R. Clark and B. F. Gupton, Chem. Commun., 2018, 54, 13343
    DOI: 10.1039/C8CC07641C

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