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A homochiral Zn–Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration

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Abstract

Both second-order nonlinear optical and single-molecule magnet properties are observed in a novel 1D homochiral Zn–Dy heterometallic left-handed helical chain complex (1) without chiral ligands, which evolves from a Zn3Dy2 pentanuclear cluster complex (2), thanks to the structural guiding role of perchlorate anions.

Graphical abstract: A homochiral Zn–Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration

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Publication details

The article was received on 14 Sep 2018, accepted on 05 Nov 2018 and first published on 05 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07468B
Citation: Chem. Commun., 2018, Advance Article
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    A homochiral Zn–Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration

    C. Liu, D. Zhang, R. Xiong, X. Hao and D. Zhu, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC07468B

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