A design strategy of reducing the molecular symmetry was used to obtain a series of picrate-based high-temperature phase transition compounds. Their dielectric switching behaviours accompanied by phase transitions can be attributed to the order–disorder transitions of the cations and the displacements of both cations and anions.
L. Zhou, P. Shi, X. Zheng, F. Geng, Q. Ye and D. Fu, Chem. Commun., 2018, 54, 13111 DOI: 10.1039/C8CC07311B
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