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A supramolecular porous material comprising Fe(II) mesocates

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Abstract

The dinuclear mesocate [Fe2L3](BF4)4, 1, is a supramolecular building block for a microporous material. Structural analysis reveals that extensive noncovalent interactions in the solid state generate a 3D framework with microporous channels. These channels are permanently accessible to incoming guest molecules and adsorption isotherms demonstrate that the material has a high selectivity for CO2 over N2.

Graphical abstract: A supramolecular porous material comprising Fe(ii) mesocates

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Publication details

The article was received on 06 Sep 2018, accepted on 05 Nov 2018 and first published on 07 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07227B
Citation: Chem. Commun., 2018, Advance Article
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    A supramolecular porous material comprising Fe(II) mesocates

    B. H. Wilson, H. S. Scott, O. T. Qazvini, S. G. Telfer, C. Mathonière, R. Clérac and P. E. Kruger, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC07227B

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