Issue 95, 2018
From the journal:

Chemical Communications

A supramolecular porous material comprising Fe(ii) mesocates†

Benjamin H. Wilson,a   Hayley S. Scott,a   Omid T. Qazvini,b   Shane G. Telfer, ORCID logo b   Corine Mathonière,cd   Rodolphe Clérac ORCID logo ef  and  Paul E. Kruger ORCID logo *a  

* Corresponding authors

a MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Physical and Chemical Sciences, University of Canterbury, Private Bag 4800, Christchurch 8041, New Zealand
E-mail: paul.kruger@canterbury.ac.nz

b MacDiarmid Institute for Advanced Materials and Nanotechnology, Institute of Fundamental Sciences, Massey University, Palmerston North 4442, New Zealand

c CNRS, ICMCB, UMR 5026, F-33600 Pessac, France

d Univ. Bordeaux, ICMCB, UMR 5026, F-33600 Pessac, France

e CNRS, CRPP, UMR 5031, F-33600 Pessac, France

f Univ. Bordeaux, CRPP, UMR 5031, F-33600 Pessac, France

Abstract

The dinuclear mesocate [Fe2L3](BF4)4, 1, is a supramolecular building block for a microporous material. Structural analysis reveals that extensive noncovalent interactions in the solid state generate a 3D framework with microporous channels. These channels are permanently accessible to incoming guest molecules and adsorption isotherms demonstrate that the material has a high selectivity for CO2 over N2.

Graphical abstract: A supramolecular porous material comprising Fe(ii) mesocates

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Article information

DOI
https://doi.org/10.1039/C8CC07227B
Article type
Communication
Submitted
06 Sep 2018
Accepted
05 Nov 2018
First published
07 Nov 2018
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2018,54, 13391-13394

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A supramolecular porous material comprising Fe(II) mesocates

B. H. Wilson, H. S. Scott, O. T. Qazvini, S. G. Telfer, C. Mathonière, R. Clérac and P. E. Kruger, Chem. Commun., 2018, 54, 13391 DOI: 10.1039/C8CC07227B

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